Lithium recycling for sustainable battery technology

Recycling lithium from spent batteries is challenging because of problems with poor purity and contamination. Here, we propose a green and sustainable lithium recovery strategy for spent batteries containing LiFePO₄, LiCoO₂, and LiNi_0.5Co_0.2Mn_0.3O₂ electrodes. Our proposed configuration of “lithium-rich electrode || LLZTO@LiTFSI+P3HT || LiOH” system achieves double-side and roll-to-roll recycling of lithium-containing electrode without destroying its integrity. The LiTFSI+P3HT-modified LLZTO membrane also solves the H⁺/Li⁺ exchange problem and realizes a waterproof protection of bare LLZTO in the aqueous working environment. On the basis of these advantages, our system shows high Li selectivity (97%) and excellent Faradaic efficiency (≥97%), achieving high-purity (99%) LiOH along with the production of H₂. The Li extraction processes for spent LiFePO₄, LiNi_0.5Co_0.2Mn_0.3O₂, and LiCoO₂ batteries is shown to be economically feasible. Therefore, this study provides a previously unexplored technology with low energy consumption as well as high economic and environmental benefits to realize sustainable lithium recycling from spent batteries.

Read the full study on Science Advances website: A green and sustainable strategy toward lithium resources recycling from spent batteries